黄原胶改性微米铁修复地下水中Cr(Ⅵ)污染的试验     

赵勇胜  李彧 《吉林大学学报(地球科学版)》2021,51(4):1224-1230

为了解决微米铁的重力沉降问题,提高微米铁修复地下水Cr（Ⅵ）污染的原位修复效果,本文利用黄原胶对微米铁进行改性,并通过沉降实验探究改性微米铁浆液的稳定性,同时选择Cr（Ⅵ）作为目标污染物,探究黄原胶改性微米铁去除地下水Cr（Ⅵ）污染的降解能力。实验结果显示：当黄原胶的投加质量浓度分别为0.0、1.0、1.5、2.0、2.5、3.0、6.0 g/L时,改性微米铁浆液的悬浮稳定性逐渐得到加强,在5 h沉降实验结束时,对应的相对分光光度值分别为0.05、0.25、0.46、0.57、0.65、0.73和0.87;黄原胶具有抑制微米铁吸附Cr（Ⅵ）的能力,其可促进Cr（Ⅵ）的还原,提高Cr（Ⅵ）的去除率;随着黄原胶投加质量浓度的增加,对应的Cr（Ⅵ）去除率分别为33.4%、41.2%、47.4%、51.1%、53.0%、63.9%和64.1%;6.0 g/L黄原胶改性的微米铁浆液具有最佳的悬浮稳定性,黄原胶的投加提高了微米铁的反应活性,但当黄原胶投加质量浓度超过3.0 g/L时,其对Cr（Ⅵ）的去除率没有显著提高;黄原胶投加质量浓度越大,黄原胶的缓冲作用就越明显。  相似文献   

利用废弃地下空间建设战略原油储备库的构想     

陈树旺  崔少东  梁久正  公繁浩  卞雄飞  张庆森 《地质与资源》2021,30(6):707-709

当前各国原油储库主要分为地面储库、地下盐穴储库和地下水封洞窟3种类型.根据我国实际情况分析,这3种类型储库均难以在我国推广.通过分析中国东北地区现有废弃矿山情况,结合地下原油储库的工程技术条件,提出了利用废弃矿山改造地下空间,用以建设战略原油储库的构想.建议尽快开展东北地区废弃矿山地下空间综合调查工作,启动相关地下油气储库封闭实验等测试研究工作.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

崩落法开采引起的岩层移动时效性研究     

刘轩廷  陈从新  夏开宗  郑先伟  王田龙  袁家好 《岩土力学》2023,(2):563-576

崩落法开采的金属矿山往往会伴随着一系列的地质灾害现象。为保证矿区安全生产,开展崩落法开采引起的岩层移动的时效性研究具有重要意义。以程潮铁矿西区下盘为研究对象,通过将地表10多年GPS监测数据的整理分析,并与现场破坏调查结果和工程地质条件相结合,进而探究不同分区下岩层移动的时效行为。研究结果表明：岩层移动的时效行为与其破坏过程有着密切的关系,不同分区下的岩层移动的时效行为是不同的,可分为初始变形、渐进变形、加速变形和残余变形共4个阶段,分别对应着稳定状态、临界状态、失稳状态以及采矿结束后的蠕变状态;初始变形阶段对应着岩体的初始蠕变过程,渐进变形阶段反映了岩体抵抗自身变形的过程,加速变形阶段与深部破坏面的形成和强烈的应力释放有关;崩落碎石在采矿作业停止后失去了流动空间,在岩体变形挤压下会对围岩提供支撑力进而限制了岩层移动的进一步发展;残余变形时间由岩体的蠕变特性和崩落碎石的压密过程所控制,倾倒滑移区因需要经历一个额外的碎石压密过程而导致残余变形时间更长。  相似文献   

塔尔塔格铁矿床——新疆阿吾拉勒铁成矿带内首例IOA型铁矿床的厘定及意义     

宋雪龙  段士刚  蒋宗胜 《地质学报》2023,97(7):2241-2260

塔尔塔格铁矿是新疆西天山阿吾拉勒海相火山岩型铁成矿带内的一处中型铁矿床,其铁矿体呈透镜状产于粗安玢岩内顶部,在揭示海相火山岩中铁矿床与侵入岩关系方面具有重要意义。该铁矿床发育典型的磁铁矿 磷灰石组合,基本不含硫化物,矿石以似斑状、浸染状、球粒状和晶洞等构造类型为特色,磁铁矿内发育由条带状或叶片状钛铁矿和钛氧化物构成的出溶结构,并有少量的榍石、钍石、萤石等副矿物与之共生,矿床地质特征表明该矿床为典型的与富碱、中性侵入岩有关的IOA（iron oxide apatite）型铁矿床。该矿床围岩英安岩、赋矿粗安玢岩与成矿后正长花岗岩的锆石SHRIMP U Pb同位素加权平均年龄分别为311. 3±1. 4 Ma、304. 7±2. 9 Ma和301. 1±2. 8 Ma,铁矿石样品中与磁铁矿共生的榍石的LA ICP MS U Pb同位素加权平均年龄为302. 3±4. 0 Ma和303. 7±4. 2 Ma,成岩成矿年龄高度吻合,进一步确定其在晚石炭世晚期成矿。本文根据地质特征认为该矿床矿石是由粗安玢岩顶部富铁挥发分聚集而形成的,并初步提出“超浅成侵入岩顶部富挥发分囊体”成矿模型,即富碱、中性岩体超浅成侵位导致挥发分在岩体顶部迅速聚集形成多处富铁和挥发分的囊体,岩体冷凝固结的同时磁铁矿快速结晶成矿。塔尔塔格“IOA型”型铁矿的成因厘定,不仅表明海相火山岩型铁矿与IOA型铁矿可能存在成因联系,还暗示了海相火山岩型铁成矿带内具有寻找IOA型铁矿的潜力。  相似文献   

1971-2015年世界铁矿石资源供需与流动格局及其演变     

王诺  张进  卢毅可  吴暖 《地理研究》2019,38(5):1253-1264

本文研究了1971—2015年世界铁矿石供需与流动格局的时空变化,结果显示：① 世界铁矿石年产量期末比期初增加了12.26亿t,年均增长2.17%;1992年以前,欧洲曾是世界铁矿石的消费重心,但随后亚洲后来居上。② 研究期内世界铁矿石输出量年均增长达3.7%,大洋洲和南美洲成为铁矿石的主要输出地,2015年占世界的比重分别达53.73%和26.23%;本世纪以来铁矿石输入量最大的是中国、日本和韩国,2015年分别占世界总量的65.07%、8.94%和5%。③ 基于“场”理论,采用位势、“源”、“汇”、迹线等概念审视全球铁矿石流场的基本特征和流场成因,发现世界铁矿石流动的“位势”北半球较低,而南半球较高;亚洲、欧洲是主要的汇流场,大洋洲、南美洲是主要的源流场。本文研究揭示了近半个世纪以来世界铁矿石资源的流动状态及其演变过程,对于我国科学地制定产业政策具有重要价值。  相似文献   

基于主成分分析法和监测数据的阿尔泰山采金废弃矿区人工恢复措施效益分析          下载免费PDF全文

艾沙江·艾力  徐海量  苑塏烨 《干旱区地理》2019,42(2):288-294

本文以阿尔泰山两河源保护区采金废弃矿区为研究区，从地形、土壤、水分和地表植被4个方面出发，结合矿区现有条件，设置11种恢复措施，选取丰富度指数、优势度指数、多样性指数、均匀度指数、生物量、植被盖度、物种数及土石比等7个评价指标，采用主成分分析法，得出不同恢复措施的主成分得分及生态效益排名。结果表明，单一恢复措施，如推平、羊群驻扎、泥浆等基本上是从某一个方面来考虑生态恢复的，存在一定的缺陷，恢复效益排名比较靠后；多种措施相结合，不仅能改善土壤环境，也会引起植物群落多样性格局的变化，生态恢复效益很好；同一种恢复措施，施行年限越长恢复效果越好。  相似文献   

Spheroidal weathering of granite porphyry with well‐developed columnar joints by oxidation,iron precipitation,and rindlet exfoliation          下载免费PDF全文

Yasuto Hirata  Masahiro Chigira  Youqing Chen 《地球表面变化过程与地形》2017,42(4):657-669

Spheroidal weathering, one of the important rock weathering styles, has been attributed to chemical weathering by the water from joint surfaces, and mechanical aspects of the weathering have not been well addressed. We made an investigation on spheroidal weathering of Miocene granite porphyry with well‐developed columnar joints and found that this spheroidal weathering proceeds through chemical processes and accompanying mechanical processes. The investigation of the textures, physical properties, mineralogy, and chemistry of the porphyry revealed the presence of a brown band on the surface margins of corestones, representing the oxidation of pyrite and chlorite, and the precipitation of iron hydroxides, and the consequent generation of micro‐cracks within the band. During weathering, oxidation progresses inwards from joints that surround the rindlets, including both high‐angle columnar and low‐angle planar joints, and causes rounding of the unweathered interior portion of the rock. Microscopic observations of the brown band embedded with fluorescent resin show that pores are first filled with iron hydroxides, and that micro‐cracks then form parallel to the oxidation front in the outer portion of the brown band. Iron hydroxide precipitation increases the P‐wave velocity in the brown band, while micro‐crack formation decreases the tensile strength of the rock. Where the brown band has thickened to ~6 cm, the micro‐cracks are connected to one another to create continuous cracks, which separate the rindlets from the corestone. Micro‐crack formation parallel to the corestone surface may be attributed to compressive stresses generated by small amounts of volumetric expansion due to the precipitation of iron hydroxides in the brown band. Earth surface is under oxidizing environments so that precipitation of iron hydroxides commonly occurs; the spheroidal weathering in this paper is a typical example of the combination of chemical and mechanical processes under such environments. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Targeting rare earth element bearing mine tailings on Bangka Island,Indonesia, with Sentinel-2 MSI     

《International Journal of Applied Earth Observation and Geoinformation》2020

A laboratory study on rare earth element bearing mine tailings, collected from Bangka Island, Indonesia, reported a new spectral absorption feature at 674 nm associated with Erbium. The present study aims to evaluate the capability of the European Space Agency’s Sentinel-2 MSI sensors to detect this absorption feature from space. An arithmetic band operation is performed on selected visible and near-infrared spectral bands of a Sentinel-2 image. The results show that Sentinel-2 MSI is capable of detecting the 674 nm Erbium-related absorption feature within the particular environmental setting of the study area.  相似文献   

唐山马家沟矿井水位异常分析     

赵建明  李红超  赵亮  董祎玮  尹宝军 《地震地磁观测与研究》2018,39(5):150-156

地下水动态受水文因素影响较大，对地震和构造活动具有较灵敏的响应。判别并排除各种水文干扰，确认地下水在地震前的异常变化，对提高地震分析预报能力，具有重要作用。马家沟矿井水位动态观测层与地下水开采层为同一含水层，井水位于2010年出现破年变异常，加速持续上升，截至2015年，最大上升幅度约30 m。依据该井水文地质环境特征，根据唐山市区2001-2015年地下水位、降雨量、地下水开采量实测资料，建立合理多元回归模型和三维地下水流动模型，发现地下水开采量减少应为影响马家沟矿井水位动态的可能因素。文中采取的异常识别与分析方法，可为其他类似井孔的地下水动态异常识别及判定提供一定借鉴。  相似文献